A6283

乙酸

glacial, ReagentPlus, ≥99%

别名:

冰乙酸

线性分子式:

CH3CO2H

CAS号:

64-19-7

分子量:

60.05

Beilstein:

506007

EC 号:

200-580-7

MDL编号:

MFCD00036152

PubChem化学物质编号:

329770889

属性

蒸汽密度

2.07 (vs air)

质量水平

200

产品线

ReagentPlus

测定

≥99%

形式

liquid

自燃温度

800°F

expl. lim.

16%, 92°F
4%, 59°F

折射率

n20/D 1.371 (lit.)

pH值（酸碱度）

2.5 (20°C, 50g/L)

bp

117-118°C (lit.)

mp

16.2°C (lit.)

溶解性

alcohol: miscible(lit.)
carbon disulfide: insoluble(lit.)
glycerol: miscible(lit.)
water: miscible(lit.)

密度

1.049g/mLat 25°C (lit.)

储存温度

room temp

SMILES string

CC(O)=O

InChI

1S/C2H4O2/c1-2(3)4/h1H3,(H,3,4)

InChI key

QTBSBXVTEAMEQO-UHFFFAOYSA-N

说明

一般描述

乙酸是一种脂肪族有机酸。[1]这是一种易吸湿的腐蚀性液体，有一种类似醋的气味。[1][2]它可以在锰或钴盐存在下氧化乙醛合成。[2]用于乙酸酐、醋酸纤维素和乙酸酯的合成。[2]已有关于它对纸张老化的影响的研究。[3]

应用

Acetic acid (AcOH) can be used as:

A reaction solvent in many organic reactions such as bromination, hydrolysis, solvolysis, reductions, and hydrogenations.

A reagent in the protonolysis of organometallic compounds.

An acetylating agent for the acetylation of electron-rich aromatic compounds.

A catalyst to synthesize di(indolyl)methanes by the condensation reaction of indole and aromatic aldehydes.

A solvent system to prepare 3,4-dihydropyrimidin-2(1H)-one derivative via Biginelli reaction of aromatic aldehydes, 1,3-dicarbonyl compounds, and urea in the presence of a boric acid catalyst.

Acetic acid can also be used in the following:

Manganese(III) acetate/AcOH catalytic system is used in the conversion of alkenes to lactones.

Iron salts/AcOH is used to oxidize 2-methylnaphthalene to 2-methyl-1-naphthol in the presence of H2O2.

包装

100, 100, 500 mL in glass bottle

1, 2.5 L in glass bottle

18 L in poly drum

特点和优势

Good stability towards many reagents

Excellent solubility of organic compounds in this reagent